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HomeMy WebLinkAboutB18-2635 MSDS Simplot UAN-32 Urea Ammonium Nitrate Solution 32-0-0 Safety Data Sheet according to Federal Register I Vol.77,No.58/Monday,March 26,2012 I Rules and Regulations •.F a V'I ,i.i�,. 1.1. Identification Product form : Mixture Product name : Simplot UAN-32 Urea Ammonium Nitrate Solution 32-0-0 Product code : M11040 1.2. Relevant identified uses of the substance or mixture and uses advised against No additional information available 1.3. Details of the supplier of the safety data sheet JR Simplot Company P.O.Box 70013 Boise,ID 83707 T 1-208-336-2110 1.4. Emergency telephone number Emergency number : CHEMTREC 1-800-424-9300 t 2.1. Classification of the substance or mixture GHS-US classification Serious eye H320 damage/eye irritation, Category 2B Full text of H statements:see section 16 2.2. Label elements GHS-US labelling Signal word(GHS-US) : Warning Hazard statements(GHS-US) : H320-Causes eye irritation Precautionary statements(GHS-US) : P264-Wash hands,forearms and face thoroughly after handling P305+P351+P338-If in eyes:Rinse cautiously with water for several minutes.Remove contact lenses,if present and easy to do.Continue rinsing P337+P313-If eye irritation persists:Get medical attention 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity(GHS US) Not applicable 21*I I..K,,. efillif rift �"�illi that"1 ri fti "iT+" »a,-; 3.1. Substance, Not applicable 3.2. Mixture Name Product identifier % ' GHS-US classification ammonium nitrate (CAS No)6484-52-2 Eye Irrit.28,H320 urea(57-13-6) (CAS No)57-13-6 Eye Irrd 2B,H320 Water ; (CAS No)7732-18-5 Not classified Full text of H-statements:see section 16 • 't 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell,seek medical advice(show the label where possible). First-aid measures after inhalation : Allow breathing of fresh air.Allow the victim to rest. 05/04/2017 EN(English) Page 1 Simplot UAN-32 Urea Ammonium Nitrate Solution 32-0-0 Safety Data Sheet according to Federal Register/Vol.77,No.58/Monday,March 26,2012/Rules and Regulations urea(57-13-6)(57-13-6) Not applicable 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Wear appropriate mask. Other information : Do not eat,drink or smoke during use. `lyrl+��►illy :tici1 "'litil•1�HE'1=1€€1+ ' f �;_ , i 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Colourless Commonly dyed blue or green Odour : There may be no odour warning properties,odour is subjective and inadequate to warn of overexposure. Mixture contains one or more component(s)which have the following odour(s): Odourless In moist air:Ammonia odour Odour threshold : No data available pH : 6.5-7 Melting point : No data available Freezing point : No data available Boiling point : 122°C Flash point : Non-flammable Relative evaporation rate(butylacetate=1) : No data available Flammability(solid,gas) : No data available Explosive limits : No data available Explosive properties : No data available Oxidising properties : No data available Vapour pressure : No data available Relative density : No data available Relative vapour density at 20°C : No data available Solubility : Complete. Water:Solubility in water of component(s)of the mixture: •ammonium nitrate: 190 g/100m1 •urea(57-13-6): 100 g/100m1 Log Pow : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity : No data available Viscosity,kinematic : No data available Viscosity,dynamic : No data available 9.2. Other information No additional information available g.+401,161€ -lt:` ('iifigt1e'r}l'r `t1 i 10.1. Reactivity No additional information available 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Not established. - 05/04/2017 EN(English) 3/6 Simplot UAN-32 Urea Ammonium Nitrate Solution 32-0-0 Safety Data Sheet according to Federal Register/Vol.77,No.58/Monday,March 26,2012/Rules and Regulations urea(57-13-6)(57-13-6) EC50 Daphnia 1 ' 10000 mg/I(48 h;Daphnia magna;Nominal concentration) LC50 fish 2 17500 mg/I(96 h;Poecilia reticulata) EC50 Daphnia 2 >10000 mg/I(24 h;Daphnia magna) j TLM fish 1 ! 17500 ppm(96 h;Poecilia reticulata) _ Threshold limit other aquatic organisms 1 i 120000 mg/I(16 h;Bacteria;Toxicity test) • I Threshold limit other aquatic organisms 2 _i.._>10000 mg/I(Pseudomonas putida) _......_........_..__._.._.........................._...............__...___........_....—...__.._............._.__.._.—_._.__..._.__._ t Threshold limit algae 1 { >10000 mg/I(168 h;Scenedesmus quadricauda;Growth rate) Threshold limit algae 2 — 47 mg/I(192 h; Microcystis aeruginosa;Growth rate) 12.2. Persistence and degradability Simplot UAN-32 Urea Ammonium Nitrate Solution 32-0-0 Persistence and degradability 'I Not established. I ammonium nitrate(6484-52-2) Persistence and degradability Biodegradable in water.Biodegradable in the soil.Not established. Water(7732-18-5) Persistence and degradability : Not established. urea(57-13-6)(57-13-6) Persistence and degradability Inherently biodegradable.Hydrolysis in water.Not established. ThOD 0.27 g 02/g substance 12.3. Bioaccumulative potential Simplot UAN-32 Urea Ammonium Nitrate Solution 32-0-0 Bioaccumulative potential Not established. ammonium nitrate(6484-5 Log Pow -3.1 Bioaccumulative potential Bioaccumulation:not applicable.Not established. Water(7732-18-5) Bioaccumulative potential j Not established. urea(57-13 6)(57-13 6) I BCF fish 1 I 1 (72 h;Brachydanio rerio;Fresh water) BCF other aquatic organisms 1 11700(Chlorella sp.)..........._......._................_.. _.. -- —..._._..__ Log Pow __..._..............._..........----._............--..----.—........--.------......_<...-1.73(Experimental value;EU Method A_8_Partition Coefficient) Bioaccumulative potential ; Bioaccumulation:not applicable.Not established. 12.4. Mobility Itf'soil No additional information available 12.5, Other adverse effects Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION _ oS otnSide l ,„£,. ,,. wpo . h , . ', „ x;.,__. . O _ MON 13.1. Waste treatment methoits Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology-waste materials : Avoid release to the environment. Department of Transportation(DOT) In accordance with DOT Not regulated for transport TDG No additional information available 05/04/2017 EN(English) 5/6